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Effects of Spiro-Cyclohexane Substitution of Nitroxyl Biradicals on Dynamic Nuclear Polarization

Spiro-substituted nitroxyl biradicals are widely used as reagents for dynamic nuclear polarization (DNP), which is especially important for biopolymer research. The main criterion for their applicability as polarizing agents is the value of the spin–spin exchange interaction parameter (<i>J</i>), wh...

Ausführliche Beschreibung

Gespeichert in:
Hauptverfasser: Nargiz B. Asanbaeva, Larisa Yu. Gurskaya, Yuliya F. Polienko, Tatyana V. Rybalova, Maxim S. Kazantsev, Alexey A. Dmitriev, Nina P. Gritsan, Nadia Haro-Mares, Torsten Gutmann, Gerd Buntkowsky, Evgeny V. Tretyakov, Elena G. Bagryanskaya
Format: Artigo
Sprache:Inglês
Veröffentlicht: MDPI AG 2022-05-01
Schriftenreihe:Molecules
Schlagworte:
EPR
nitroxide
biradical
ferrocene
exchange interaction
DNP
Online-Zugang:https://www.mdpi.com/1420-3049/27/10/3252
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