The Synthesis of a Strained Bridgehead Olefin by an Intramolecular Wittig Reaction
A number of olefins with the double bond at the bridgehead was synthesized by an intramolecular Wittig reaction starting from 2-(bromoalkyl) cyclanones. The ring closure of 3-(3-oxocyclohexyl) propyltriphenylphosphonium bromide leads to the strained bridgehead olefin (“Bredt-olefin”) bicyclo[3.3.l]...
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| 第一著者: | |
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| フォーマット: | Artigo |
| 言語: | Alemão |
| 出版事項: |
Swiss Chemical Society
1974-12-01
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| シリーズ: | CHIMIA |
| オンライン･アクセス: | https://www.chimia.ch/chimia/article/view/9191 |
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