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Synthesis and Absolute Configuration of (20R)-20-Acetyl-23,24- bisnorcholanic Lactones Prepared from (E)-(20S,25R)- and (E)-(20S,25S)- 20,23-Diacetylfurost-22-enes
The synthesis of (20R)-20-acetyl-23,24-bisnorcholaniclactones from (E)-(20S,25R)- and (E)-(20S,25R)-20,23-diacetylfurost-22-enes (derived from diosgenin, hecogenin and sarsasapogenin)is reported. The configuration of the stereogenic center at C-20 wasdetermined by NMR and single crystal X-ray diffra...
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| Yayımlandı: | Journal of the Mexican Chemical Society |
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| Asıl Yazarlar: | , , , , , |
| Materyal Türü: | Artigo |
| Dil: | Inglês |
| Baskı/Yayın Bilgisi: |
Sociedad Química de México
2007
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| Konular: | |
| Online Erişim: | https://www.redalyc.org/articulo.oa?id=47551409 |
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