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An Alternative Approach to Aminodiols from Baylis-Hillman Adducts. Stereoselective Synthesis of Chloramphenicol, Fluoramphenicol and Thiamphenicol
We describe herein a new approach for the stereoselective synthesis of broad spectrum antibioticsfrom Baylis-Hillman adducts. The strategy is based on the preparation of an ene-carbamate directlyfrom a Baylis-Hillman adduct using a Curtius rearrangement reaction. Stereoselective hydroborationfurnish...
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| Vydáno v: | Journal of the Mexican Chemical Society |
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| Hlavní autoři: | , |
| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
Sociedad Química de México
2005
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| Témata: | |
| On-line přístup: | https://www.redalyc.org/articulo.oa?id=47549212 |
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