Enantioselective epoxidation of styrene using in-situ generated dimethyldioxirane and dimeric homochiral Mn(III)-Schiff base complex catalyst

The enantioselective epoxidation of styrene using in-situ generated dimethyldioxirane (DMD) and dimeric homochiral Mn(III)-Schiff base catalyst 1 has been explored. The parameters evaluated were olefin/oxidant molar ration, catalyst loading, reaction temperature and presence of nitrogen coordinating...

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Detalhes bibliográficos
Publicado no:Revista Facultad de Ingeniería Universidad de Antioquia
Main Authors: Brayan David Verdugo-Torres, Jairo Antonio Cubillos-Lobo, Hugo Alfonso Rojas-Sarmiento
Formato: Artigo
Idioma:Inglês
Publicado em: Universidad de Antioquia 2018
Assuntos:
Ingeniería
Styrene
Dimeric catalyst
Dimethyldioxirane
catalysts reusability
Enantioselective epoxidation
Acesso em linha:https://www.redalyc.org/articulo.oa?id=43060744010
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