Jacobsen’s catalyst anchored on Al-MCM-41 and NH2 group modified Si-MCM-41 as heterogeneous enantioselective epoxidation catalyst using in situ generated dimethyldioxirane as oxidant

The enantioselective epoxidation of three prochiral olefins over Jacobsen’s catalyst immobilized on Al-MCM-41 and NH2-Si-MCM-41 in the presence of in situ generated DMD as the oxygen source was investigated. Experimental results indicate that the catalyst did not significantly suffer any change in i...

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Опубликовано в: :Revista Facultad de Ingeniería Universidad de Antioquia
Главные авторы: Jairo Cubillos, Wolfgang Hölderich
Формат: Artigo
Язык:Inglês
Опубликовано: Universidad de Antioquia 2007
Предметы:
Ingeniería
recyclability
Jacobsen’s catalyst
Immobilized catalyst
catalyst degradation
in situ generated DMD
Online-ссылка:https://www.redalyc.org/articulo.oa?id=43004104
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