Assignment of protonated R-homocitrate in extracted FeMo-cofactor of nitrogenase via vibrational circular dichroism spectroscopy

Protonation of FeMo-cofactor (FeMo-co) is important for the process of substrate hydrogenation. Its structure has been clarified as Δ-Mo*Fe(7)S(9)C(R-homocit*)(cys)(Hhis) after the efforts of nearly 30 years, but it remains controversial whether FeMo-co is protonated or deprotonated with chelated ≡C...

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Bibliografski detalji
Izdano u:Commun Chem
Glavni autori: Deng, Lan, Wang, Hongxin, Dapper, Christie H., Newton, William E., Shilov, Sergey, Wang, Shunlin, Cramer, Stephen P., Zhou, Zhao-Hui
Format: Artigo
Jezik:Inglês
Izdano: Nature Publishing Group UK 2020
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Article
Online pristup:https://ncbi.nlm.nih.gov/pmc/articles/PMC8323615/
https://ncbi.nlm.nih.gov/pubmed/34337161
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s42004-020-00392-z
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