Structure and spectroscopy of a bidentate bis-homocitrate dioxo-molybdenum(VI) complex: Insights relevant to the structure and properties of the FeMo-cofactor in nitrogenase

Direct reaction of potassium molybdate (with natural abundance Mo or enriched with (92)Mo or (100)Mo) with excess hydrolyzed homocitric acid-γ-lactone in acidic solution resulted in the isolation of a cis-dioxo bis-homocitrato molybdenum(VI) complex, K(2)[*MoO(2)(R,S-H(2)homocit)(2)]·2H(2)O (1) (*Mo...

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Bibliografiske detaljer
Main Authors: Zhou, Zhao-Hui, Wang, Hongxin, Yu, Ping, Olmstead, Marilyn M., Cramer, Stephen P.
Format: Artigo
Sprog:Inglês
Udgivet: 2012
Fag:
Article
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC3596267/
https://ncbi.nlm.nih.gov/pubmed/23147649
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.jinorgbio.2012.10.001
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