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Ligand binding to the FeMo-cofactor: structures of CO-bound and reactivated nitrogenase
The mechanism of nitrogenase remains enigmatic, with a major unresolved issue concerning how inhibitors and substrates bind to the active site. We report a crystal structure of carbon monoxide (CO) inhibited nitrogenase MoFe-protein at 1.50 Å resolution, revealing a CO molecule bridging Fe2 and Fe6...
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| Main Authors: | , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2014
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4205161/ https://ncbi.nlm.nih.gov/pubmed/25258081 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.1256679 |
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