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Simultaneous construction of axial and planar chirality by gold/TY-Phos-catalyzed asymmetric hydroarylation

The simultaneous construction of two different chiralities via a simple operation poses considerable challenge. Herein a cationic gold-catalyzed asymmetric hydroarylation of ortho-alkynylaryl ferrocenes derivatives is developed, which enable the simultaneous construction of axial and planar chiralit...

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Publicado en:Nat Commun
Autores principales: Zhang, Pei-Chao, Li, Yin-Lin, He, Jiafeng, Wu, Hai-Hong, Li, Zhiming, Zhang, Junliang
Formato: Artigo
Lenguaje:Inglês
Publicado: Nature Publishing Group UK 2021
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC8322429/
https://ncbi.nlm.nih.gov/pubmed/34326337
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/s41467-021-24678-5
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