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Ligand Substitution and Electronic Structure Studies of Bis(phosphine)Cobalt Cyclooctadiene Precatalysts for Alkene Hydrogenation

Diene self-exchange reactions of the 17-electron, formally cobalt(0) cyclooctadienyl precatalyst, (R,R)-((iPr)DuPhos)Co(COD) (P(2)CoCOD, (R,R)-(iPr)DuPhos = 1,2-bis((2R,5R)-2,5-diisopropylphospholano)benzene, COD = 1,5-cyclooctadiene) were studied using natural abundance and deuterated 1,5-cycloocta...

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Detalhes bibliográficos
Publicado no:Can J Chem
Main Authors: Zhong, Hongyu, Beromi, Megan Mohadjer, Chirik, Paul J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2020
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8317443/
https://ncbi.nlm.nih.gov/pubmed/34334799
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1139/cjc-2020-0352
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