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Structure, Spectroscopy, and Reactivity of a Mononuclear Copper Hydroxide Complex in Three Molecular Oxidation States

Structural, spectroscopic, and reactivity studies are presented for an electron transfer series of copper hydroxide complexes supported by a tridentate redox-active ligand. Single crystal X-ray crystallography shows that the mononuclear [CuOH](1+) core is stabilized via intramolecular H-bonds betwee...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Wu, Tong, MacMillan, Samantha N., Rajabimoghadam, Khashayar, Siegler, Maxime A., Lancaster, Kyle M., Garcia-Bosch, Isaac
Formato: Artigo
Idioma:Inglês
Publicado em: 2020
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Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8300862/
https://ncbi.nlm.nih.gov/pubmed/32531159
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c03867
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