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Bioorthogonal Hydroamination of Push-Pull-Activated Linear Alkynes
A bioorthogonal reaction between N,N-dialkylhydroxylamines and push-pull-activated halogenated alkynes is described. We explore the use of rehybridization effects in activating alkynes, and we show that electronic effects, when competing stereoelectronic and inductive factors are properly balanced,...
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| Publicado en: | Angew Chem Int Ed Engl |
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| Autores principales: | , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2021
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8292212/ https://ncbi.nlm.nih.gov/pubmed/34019705 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202104863 |
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