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Allene Trifunctionalization via Amidyl Radical Cyclization and TEMPO Trapping
Radical-mediated trifunctionalizations of allenes are virtually unknown, in contrast to well-studied radical difunctionalizations of alkenes and alkynes. In this communication, we describe a light-promoted reaction that transforms all three allene carbons to new carbon-heteroatom bonds in one pot wi...
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| Publicat a: | J Org Chem |
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| Autors principals: | , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2021
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8290888/ https://ncbi.nlm.nih.gov/pubmed/34125539 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.1c00675 |
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