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Enantioselective Intermolecular C–H Amination Directed by a Chiral Cation

[Image: see text] The enantioselective amination of C(sp(3))–H bonds is a powerful synthetic transformation yet highly challenging to achieve in an intermolecular sense. We have developed a family of anionic variants of the best-in-class catalyst for Rh-catalyzed C–H amination, Rh(2)(esp)(2), with w...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Fanourakis, Alexander, Williams, Benjamin D., Paterson, Kieran J., Phipps, Robert J.
Formato: Artigo
Idioma:Inglês
Publicado em: American Chemical Society 2021
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8283762/
https://ncbi.nlm.nih.gov/pubmed/34181401
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.1c05206
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