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Synthesis of cis-Oriented Vicinal Diphenylethylenes through a Lewis Acid-Promoted Annulation of Oxotriphenylhexanoates

[Image: see text] This study explores the synthesis of cyclic cis-vicinal phenyl ethylenes from oxotriphenylhexanoates. The reaction is a BBr(3)-promoted cyclization of 1,6-ketoesters (1) to five-membered diketo compounds (2). The synthesis is interesting as it constitutes one of the few examples of...

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Vydáno v:J Org Chem
Hlavní autoři: Kamlar, Martin, Henriksson, Elin, Císařová, Ivana, Malo, Marcus, Sundén, Henrik
Médium: Artigo
Jazyk:Inglês
Vydáno: American Chemical Society 2021
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC8279482/
https://ncbi.nlm.nih.gov/pubmed/34138578
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.joc.1c00445
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