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Origin of the Non-Arrhenius Behavior of the Rates of Enzymatic Reactions

The origin of the non-Arrhenius behavior of the rate constant for hydride transfer enzymatic reactions has been a puzzling problem since its initial observation. This effect has been used originally to support the idea that enzymes work by dynamical effects and more recently to suggest an entropy fu...

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Bibliographic Details
Published in:J Phys Chem B
Main Authors: Roy, Subhendu, Schopf, Patrick, Warshel, Arieh
Format: Artigo
Language:Inglês
Published: 2017
Subjects:
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC8269111/
https://ncbi.nlm.nih.gov/pubmed/28613876
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.jpcb.7b03698
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