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Phosphite mediated asymmetric N to C migration for the synthesis of chiral heterocycles from primary amines
A phosphite mediated stereoretentive C–H alkylation of N-alkylpyridinium salts derived from chiral primary amines was achieved. The reaction proceeds through the activation of the N-alkylpyridinium salt substrate with a nucleophilic phosphite catalyst, followed by a base mediated [1,2] aza-Wittig re...
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| Vydáno v: | Chem Sci |
|---|---|
| Hlavní autoři: | , , , , , |
| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
The Royal Society of Chemistry
2021
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8261767/ https://ncbi.nlm.nih.gov/pubmed/34276927 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1sc01217g |
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