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B–B vs. B–H Bond Activation in a (μ‐Hydrido)diborane(4) Anion upon Cycloaddition with CO(2), Isocyanates, or Carbodiimides

The intriguing (μ‐hydrido)diboranes(4) with their prominent pristine representative [B(2)H(5)](−) have mainly been studied theoretically. We now describe the behavior of the planarized tetraaryl (μ‐hydrido)diborane(4) anion [1H](−) in cycloaddition reactions with the homologous series of heterocumul...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Trageser, Timo, Bebej, Dariusz, Bolte, Michael, Lerner, Hans‐Wolfram, Wagner, Matthias
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2021
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8252796/
https://ncbi.nlm.nih.gov/pubmed/33740318
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202103427
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