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A Protecting‐Group‐Free Synthesis of (−)‐Salvinorin A
A concise enantioselective total synthesis of the neoclerodane diterpene (−)‐salvinorin A is reported. The stereogenic center at C‐12 was installed by catalytic asymmetric propargylation with excellent enantioselectivity, and the remaining six stereogenic centers were set up highly diastereoselectiv...
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| Vydáno v: | Chemistry |
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| Hlavní autoři: | , , |
| Médium: | Artigo |
| Jazyk: | Inglês |
| Vydáno: |
John Wiley and Sons Inc.
2021
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| Témata: | |
| On-line přístup: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8252117/ https://ncbi.nlm.nih.gov/pubmed/33784436 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202100560 |
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