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A Novel M(8)L(6) Cubic Cage That Binds Tetrapyridyl Porphyrins: Cage and Solvent Effects in Cobalt‐Porphyrin‐Catalyzed Cyclopropanation Reactions

Confinement of a catalyst can have a significant impact on catalytic performance and can lead to otherwise difficult to achieve catalyst properties. Herein, we report the design and synthesis of a novel caged catalyst system Co−G@Fe(8)(Zn−L ⋅ 1)(6), which is soluble in both polar and apolar solvents...

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Detalhes bibliográficos
Publicado no:Chemistry
Main Authors: Mouarrawis, Valentinos, Bobylev, Eduard O., de Bruin, Bas, Reek, Joost N. H.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2021
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8252039/
https://ncbi.nlm.nih.gov/pubmed/33780040
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.202100344
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