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Tuning the Porphyrin Building Block in Self‐Assembled Cages for Branched‐Selective Hydroformylation of Propene
Unprecedented regioselectivity to the branched aldehyde product in the hydroformylation of propene was attained on embedding a rhodium complex in supramolecular assembly L2, formed by coordination‐driven self‐assembly of tris(meta‐pyridyl)phosphine and zinc(II) porpholactone. The design of cage L2 i...
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| Publicado en: | Chemistry |
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| Autores principales: | , , , , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
John Wiley and Sons Inc.
2017
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5697640/ https://ncbi.nlm.nih.gov/pubmed/28608592 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201702113 |
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