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Tuning the Porphyrin Building Block in Self‐Assembled Cages for Branched‐Selective Hydroformylation of Propene

Unprecedented regioselectivity to the branched aldehyde product in the hydroformylation of propene was attained on embedding a rhodium complex in supramolecular assembly L2, formed by coordination‐driven self‐assembly of tris(meta‐pyridyl)phosphine and zinc(II) porpholactone. The design of cage L2 i...

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Bibliografske podrobnosti
izdano v:Chemistry
Main Authors: Wang, Xiaowu, Nurttila, Sandra S., Dzik, Wojciech I., Becker, René, Rodgers, Jody, Reek, Joost N. H.
Format: Artigo
Jezik:Inglês
Izdano: John Wiley and Sons Inc. 2017
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC5697640/
https://ncbi.nlm.nih.gov/pubmed/28608592
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/chem.201702113
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