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Chasing the Mond Cation: Synthesis and Characterization of the Homoleptic Nickel Tetracarbonyl Cation and its Tricarbonyl‐Nitrosyl Analogue
130 years after Mond discovered the first homoleptic carbonyl complex Ni(CO)(4), we report on a [Ni(CO)(4)](.+) salt as the first synthesis of any homoleptic nickel carbonyl cation in the condensed phase. It was prepared by oxidation of nickel metal with the synergistic oxidant Ag[F{Al(OR(F))(3)}(2)...
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| Publicado en: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8251987/ https://ncbi.nlm.nih.gov/pubmed/33734545 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202102216 |
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