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Enantioselective Alkoxycyclization of 1,6‐Enynes with Gold(I)‐Cavitands: Total Synthesis of Mafaicheenamine C

Chiral gold(I)‐cavitand complexes have been developed for the enantioselective alkoxycyclization of 1,6‐enynes. This enantioselective cyclization has been applied for the first total synthesis of carbazole alkaloid (+)‐mafaicheenamine C and its enantiomer, establishing its configuration as R. The ca...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Martín‐Torres, Inmaculada, Ogalla, Gala, Yang, Jin‐Ming, Rinaldi, Antonia, Echavarren, Antonio M.
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2021
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8251978/
https://ncbi.nlm.nih.gov/pubmed/33576560
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202017035
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