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Late‐Stage Heteroarylation of Hetero(aryl)sulfonium Salts Activated by α‐Amino Alkyl Radicals

We report a late‐stage heteroarylation of aryl sulfonium salts through activation with α‐amino alkyl radicals in a mechanistically distinct approach from previously reported halogen‐atom transfer (XAT). The new mode of activation of aryl sulfonium salts proceeds in the absence of light and photoredo...

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Pubblicato in:Angew Chem Int Ed Engl
Autori principali: Alvarez, Eva Maria, Karl, Teresa, Berger, Florian, Torkowski, Luca, Ritter, Tobias
Natura: Artigo
Lingua:Inglês
Pubblicazione: John Wiley and Sons Inc. 2021
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC8251951/
https://ncbi.nlm.nih.gov/pubmed/33835680
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202103085
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