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Aryl Sulfonium Salts for Site‐Selective Late‐Stage Trifluoromethylation
Incorporation of the CF(3) group into arenes has found increasing importance in drug discovery. Herein, we report the first photoredox‐catalyzed cross‐coupling of aryl thianthrenium salts with a copper‐based trifluoromethyl reagent, which enables a site‐selective late‐stage trifluoromethylation of a...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2019
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7754511/ https://ncbi.nlm.nih.gov/pubmed/31389649 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201906672 |
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