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Diversifying Metal–Ligand Cooperative Catalysis in Semi‐Synthetic [Mn]‐Hydrogenases
The reconstitution of [Mn]‐hydrogenases using a series of Mn(I) complexes is described. These complexes are designed to have an internal base or pro‐base that may participate in metal–ligand cooperative catalysis or have no internal base or pro‐base. Only Mn(I) complexes with an internal base or pro...
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| Publicado no: | Angew Chem Int Ed Engl |
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| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
John Wiley and Sons Inc.
2021
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8251902/ https://ncbi.nlm.nih.gov/pubmed/33635597 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202100443 |
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