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Diversifying Metal–Ligand Cooperative Catalysis in Semi‐Synthetic [Mn]‐Hydrogenases

The reconstitution of [Mn]‐hydrogenases using a series of Mn(I) complexes is described. These complexes are designed to have an internal base or pro‐base that may participate in metal–ligand cooperative catalysis or have no internal base or pro‐base. Only Mn(I) complexes with an internal base or pro...

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Bibliografiske detaljer
Udgivet i:Angew Chem Int Ed Engl
Main Authors: Pan, Hui‐Jie, Huang, Gangfeng, Wodrich, Matthew D., Tirani, Farzaneh Fadaei, Ataka, Kenichi, Shima, Seigo, Hu, Xile
Format: Artigo
Sprog:Inglês
Udgivet: John Wiley and Sons Inc. 2021
Fag:
Online adgang:https://ncbi.nlm.nih.gov/pmc/articles/PMC8251902/
https://ncbi.nlm.nih.gov/pubmed/33635597
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202100443
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