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Ortho-aryl substituted DPEphos ligands: rhodium complexes featuring C–H anagostic interactions and B–H agostic bonds
The synthesis of new Schrock–Osborn Rh(i) pre-catalysts with ortho-substituted DPEphos ligands, [Rh(DPEphos-R)(NBD)][BAr(F)(4)] [R = Me, OMe, (i)Pr; Ar(F) = 3,5-(CF(3))(2)C(6)H(3)], is described. Along with the previously reported R = H variant, variable temperature (1)H NMR spectroscopic and single...
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| Publié dans: | Chem Sci |
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| Auteurs principaux: | , , , , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
The Royal Society of Chemistry
2021
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8246285/ https://ncbi.nlm.nih.gov/pubmed/34257884 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1sc01430g |
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