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De Novo Synthesis of an l-Lemonose Thioglycoside Donor from d-Threonine
A short de novo synthesis of an l-lemonose thioglycoside is described starting from d-threonine. The synthesis leverages a Dieckmann condensation and Stork-Danheiser transposition to arrive at a key vinylogous ester intermediate on gram scale. Ensuing 1,2-addition diastereoselectively establishes th...
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| Udgivet i: | Tetrahedron Lett |
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| Main Authors: | , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2021
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8224840/ https://ncbi.nlm.nih.gov/pubmed/34176980 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2021.153097 |
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