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Intercepting the Banert Cascade with Nucleophilic Fluorine: Direct Access to α-Fluorinated NH-1,2,3-Triazoles

The treatment of propargylic azides with silver (I) fluoride in acetonitrile was found to yield α-fluorinated NH-1,2,3-triazoles via the Banert Cascade. The reaction was regioselective and the products result from an initial [3,3] rearrangement. The reaction is demonstrated on >15 examples with y...

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Publicado en:Chem Commun (Camb)
Main Authors: Alexander, J. A., Kevorkian, P. V., Topczewski, J. J.
Formato: Artigo
Idioma:Inglês
Publicado: 2021
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC8201930/
https://ncbi.nlm.nih.gov/pubmed/33890592
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1cc01179k
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