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Intercepting the Banert Cascade with Nucleophilic Fluorine: Direct Access to α-Fluorinated NH-1,2,3-Triazoles
The treatment of propargylic azides with silver (I) fluoride in acetonitrile was found to yield α-fluorinated NH-1,2,3-triazoles via the Banert Cascade. The reaction was regioselective and the products result from an initial [3,3] rearrangement. The reaction is demonstrated on >15 examples with y...
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| Publicado en: | Chem Commun (Camb) |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2021
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8201930/ https://ncbi.nlm.nih.gov/pubmed/33890592 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1cc01179k |
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