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Silver Mediated Banert Cascade with Carbon Nucleophiles
The Banert cascade of propargylic azides can be promoted by simple silver salts, and the triazafulvene intermediate can be intercepted by carbon nucleophiles. Various indoles (>25 examples, up to 92% yield) and electron-rich heterocycles were effective. The Mayr nucleophilicity parameter (N) was...
Guardat en:
| Publicat a: | Org Lett |
|---|---|
| Autors principals: | , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2021
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8120647/ https://ncbi.nlm.nih.gov/pubmed/33797930 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.1c01032 |
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