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Remote Allylation of Unactivated C(sp(3))–H Bonds Triggered by Photogenerated Amidyl Radicals

The allylation reaction is a highly versatile transformation in chemical synthesis. While many elegant direct C(sp(2))–H allylation reactions have been developed, the direct allylation of unactivated C(sp(3))–H bonds is underdeveloped. By applying photoredox catalysis and a [1,5]-HAT process, herein...

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Detalhes bibliográficos
Publicado no:ACS Catal
Main Authors: Xu, Bin, Tambar, Uttam K.
Formato: Artigo
Idioma:Inglês
Publicado em: 2019
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC8186322/
https://ncbi.nlm.nih.gov/pubmed/34109055
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.9b00563
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