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Selective Manganese-Catalyzed Dimerization and Cross-Coupling of Terminal Alkynes

[Image: see text] Herein, efficient manganese-catalyzed dimerization of terminal alkynes to afford 1,3-enynes is described. This reaction is atom economic, implementing an inexpensive, earth-abundant nonprecious metal catalyst. The precatalyst is the bench-stable alkyl bisphosphine Mn(I) complex fac...

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Detalles Bibliográficos
Publicado en:ACS Catal
Main Authors: Weber, Stefan, Veiros, Luis F., Kirchner, Karl
Formato: Artigo
Idioma:Inglês
Publicado: American Chemical Society 2021
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC8185884/
https://ncbi.nlm.nih.gov/pubmed/34123484
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acscatal.1c01137
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