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Construction of congested Csp(3)–Csp(3) bonds by a formal Ni-catalyzed alkylboration

Through the combination of a Ni-catalyzed alkene alkenylboration followed by hydrogenation, the synthesis of congested Csp(3)–Csp(3)-bonds can be achieved. Conditions have been identified that allow for the use of both alkenyl-bromides and -triflates. In addition, the hydrogenation creates another o...

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Pubblicato in:Chem Sci
Autori principali: Simlandy, Amit Kumar, Sardini, Stephen R., Brown, M. Kevin
Natura: Artigo
Lingua:Inglês
Pubblicazione: The Royal Society of Chemistry 2021
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Accesso online:https://ncbi.nlm.nih.gov/pmc/articles/PMC8179681/
https://ncbi.nlm.nih.gov/pubmed/34168789
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1sc00900a
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