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Photoactive electron donor–acceptor complex platform for Ni-mediated C(sp(3))–C(sp(2)) bond formation

A dual photochemical/nickel-mediated decarboxylative strategy for the assembly of C(sp(3))–C(sp(2)) linkages is disclosed. Under light irradiation at 390 nm, commercially available and inexpensive Hantzsch ester (HE) functions as a potent organic photoreductant to deliver catalytically active Ni(0)...

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發表在:Chem Sci
Main Authors: Kammer, Lisa Marie, Badir, Shorouk O., Hu, Ren-Ming, Molander, Gary A.
格式: Artigo
語言:Inglês
出版: The Royal Society of Chemistry 2021
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在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC8179655/
https://ncbi.nlm.nih.gov/pubmed/34168786
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d1sc00943e
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