Catalytic asymmetric synthesis of N-substituted tetrahydroquinoxalines via regioselective Heyns rearrangement and stereoselective transfer hydrogenation in one pot

N-Substituted tetrahydroquinoxalines (37 examples) were step-economically obtained in good yield (<97%) and ee (<99%) with readily available substrates. The reaction proceeds through an interesting regioselective Heyns rearrangement/enantioselective transfer hydrogenation in one pot. The subst...

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Vydáno v:Chem Sci
Hlavní autoři: Huang, Jin, Li, Guang-xun, Yang, Gao-feng, Fu, Ding-qiang, Nie, Xiao-kang, Cui, Xin, Zhao, Jin-zhong, Tang, Zhuo
Médium: Artigo
Jazyk:Inglês
Vydáno: The Royal Society of Chemistry 2021
Témata:
Chemistry
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC8179646/
https://ncbi.nlm.nih.gov/pubmed/34168757
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc06264b
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