Soluble, crystalline, and thermally stable alkali CO(2)(−) and carbonite (CO(2)(2−)) clusters supported by cyclic(alkyl)(amino) carbenes

The mono- and dianions of CO(2) (i.e., CO(2)(−) and CO(2)(2−)) have been studied for decades as both fundamentally important oxycarbanions (anions containing only C and O atoms) and as critical species in CO(2) reduction and fixation chemistry. However, CO(2) anions are highly unstable and difficult...

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Vydáno v:Chem Sci
Hlavní autoři: Freeman, Lucas A., Obi, Akachukwu D., Machost, Haleigh R., Molino, Andrew, Nichols, Asa W., Dickie, Diane A., Wilson, David J. D., Machan, Charles W., Gilliard, Robert J.
Médium: Artigo
Jazyk:Inglês
Vydáno: The Royal Society of Chemistry 2021
Témata:
Chemistry
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC8179443/
https://ncbi.nlm.nih.gov/pubmed/34163627
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc06851a
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