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Gold-catalyzed (4 + 2)-annulations between α-alkyl alkenylgold carbenes and benzisoxazoles with reactive alkyl groups

This work reports new (4 + 2)-annulations of α-alkyl vinylgold carbenes with benzisoxazoles to afford 3,4-dihydroquinoline derivatives with high anti-stereoselectivity. The annulations are operable with carbenes in both acyclic and cyclic forms. This reaction sequence involves an initial formation o...

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Detalhes bibliográficos
Publicado no:Chem Sci
Main Authors: Mokar, Bhanudas Dattatray, Jadhav, Prakash D., Pandit, Y. B., Liu, Rai-Shung
Formato: Artigo
Idioma:Inglês
Publicado em: Royal Society of Chemistry 2018
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6049024/
https://ncbi.nlm.nih.gov/pubmed/30079175
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c8sc00986d
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