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Photocatalyst-independent photoredox ring-opening polymerization of O-carboxyanhydrides: stereocontrol and mechanism

Photoredox ring-opening polymerization of O-carboxyanhydrides allows for the synthesis of polyesters with precisely controlled molecular weights, molecular weight distributions, and tacticities. While powerful, obviating the use of precious metal-based photocatalysts would be attractive from the per...

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Publicado en:Chem Sci
Autores principales: Zhong, Yongliang, Feng, Quanyou, Wang, Xiaoqian, Yang, Lei, Korovich, Andrew G., Madsen, Louis A., Tong, Rong
Formato: Artigo
Lenguaje:Inglês
Publicado: The Royal Society of Chemistry 2021
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC8179436/
https://ncbi.nlm.nih.gov/pubmed/34163644
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc05550f
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