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Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes

Here, we describe an effective protocol that combines photoredox Ni/Ir catalysis with the use of a Zn-alkoxide for efficient ring-opening polymerization, allowing for the synthesis of isotactic poly(α-hydroxy acids) with expected molecular weights (>140 kDa) and narrow molecular weight distributi...

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Detalhes bibliográficos
Publicado no:J Vis Exp
Main Authors: Feng, Quanyou, Tong, Rong
Formato: Artigo
Idioma:Inglês
Publicado em: MyJove Corporation 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5755454/
https://ncbi.nlm.nih.gov/pubmed/29286388
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3791/56654
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