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Dehydrogenation of iron amido-borane and resaturation of the imino-borane complex
We report on the first isolation and structural characterization of an iron phosphinoimino-borane complex Cp*Fe(η(2)-H(2)B[double bond, length as m-dash]NC(6)H(4)PPh(2)) by dehydrogenation of iron amido-borane precursor Cp*Fe(η(1)-H(3)B–NHC(6)H(4)PPh(2)). Significantly, regeneration of the amido-bor...
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| Publicado en: | Chem Sci |
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| Main Authors: | , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
The Royal Society of Chemistry
2021
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8179412/ https://ncbi.nlm.nih.gov/pubmed/34164054 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc06787c |
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