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Dehydrogenation of iron amido-borane and resaturation of the imino-borane complex

We report on the first isolation and structural characterization of an iron phosphinoimino-borane complex Cp*Fe(η(2)-H(2)B[double bond, length as m-dash]NC(6)H(4)PPh(2)) by dehydrogenation of iron amido-borane precursor Cp*Fe(η(1)-H(3)B–NHC(6)H(4)PPh(2)). Significantly, regeneration of the amido-bor...

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Dades bibliogràfiques
Publicat a:Chem Sci
Autors principals: Zhai, Xiaofang, Pang, Maofu, Feng, Lei, Jia, Jiong, Tung, Chen-Ho, Wang, Wenguang
Format: Artigo
Idioma:Inglês
Publicat: The Royal Society of Chemistry 2021
Matèries:
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC8179412/
https://ncbi.nlm.nih.gov/pubmed/34164054
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc06787c
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