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Synthesis, bonding properties and ether activation reactivity of cyclobutadienyl-ligated hybrid uranocenes
A series of hybrid uranocenes consisting of uranium(iv) sandwiched between cyclobutadienyl (Cb) and cyclo-octatetraenyl (COT) ligands has been synthesized, structurally characterized and studied computationally. The dimetallic species [(η(4)-Cb′′′′)(η(8)-COT)U(μ:η(2):η(8)-COT)U(THF)(η(4)-Cb′′′′)] (1...
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| Pubblicato in: | Chem Sci |
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| Autori principali: | , , |
| Natura: | Artigo |
| Lingua: | Inglês |
| Pubblicazione: |
The Royal Society of Chemistry
2021
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| Soggetti: | |
| Accesso online: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8179396/ https://ncbi.nlm.nih.gov/pubmed/34164062 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc05199c |
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