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Boosting homogeneous chemoselective hydrogenation of olefins mediated by a bis(silylenyl)terphenyl-nickel(0) pre-catalyst
The isolable chelating bis(N-heterocyclic silylenyl)-substituted terphenyl ligand [Si(II)(Terp)Si(II)] as well as its bis(phosphine) analogue [P(III)(Terp)P(III)] have been synthesised and fully characterised. Their reaction with Ni(cod)(2) (cod = cycloocta-1,5-diene) affords the corresponding 16 VE...
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| Publicado no: | Chem Sci |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
The Royal Society of Chemistry
2021
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8179395/ https://ncbi.nlm.nih.gov/pubmed/34164057 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc06471h |
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