Divergent Reactivity of a Dinuclear (NHC)Nickel(I) Catalyst versus Nickel(0) Enables Chemoselective Trifluoromethylselenolation

We herein showcase the ability of NHC‐coordinated dinuclear Ni(I)–Ni(I) complexes to override fundamental reactivity limits of mononuclear (NHC)Ni(0) catalysts in cross‐couplings. This is demonstrated with the development of a chemoselective trifluoromethylselenolation of aryl iodides catalyzed by a...

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Bibliografische gegevens
Gepubliceerd in:Angew Chem Int Ed Engl
Hoofdauteurs: Dürr, Alexander B., Fisher, Henry C., Kalvet, Indrek, Truong, Khai‐Nghi, Schoenebeck, Franziska
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: John Wiley and Sons Inc. 2017
Onderwerpen:
Communications
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC5656904/
https://ncbi.nlm.nih.gov/pubmed/28795520
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201706423
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