Divergent Reactivity of a Dinuclear (NHC)Nickel(I) Catalyst versus Nickel(0) Enables Chemoselective Trifluoromethylselenolation

We herein showcase the ability of NHC‐coordinated dinuclear Ni(I)–Ni(I) complexes to override fundamental reactivity limits of mononuclear (NHC)Ni(0) catalysts in cross‐couplings. This is demonstrated with the development of a chemoselective trifluoromethylselenolation of aryl iodides catalyzed by a...

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Detalhes bibliográficos
Publicado no:Angew Chem Int Ed Engl
Main Authors: Dürr, Alexander B., Fisher, Henry C., Kalvet, Indrek, Truong, Khai‐Nghi, Schoenebeck, Franziska
Formato: Artigo
Idioma:Inglês
Publicado em: John Wiley and Sons Inc. 2017
Assuntos:
Communications
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5656904/
https://ncbi.nlm.nih.gov/pubmed/28795520
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201706423
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