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Ultrafast structural dynamics of in-cage isomerization of diiodomethane in solution

Despite extensive studies on the isomer species formed by photodissociation of haloalkanes in solution, the molecular structure of the precursor of the isomer, which is often assumed to be a vibrationally hot isomer formed from the radical pair, and its in-cage isomerization mechanism remain elusive...

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Publicado en:Chem Sci
Autores principales: Kim, Hanui, Kim, Jong Goo, Kim, Tae Wu, Lee, Sang Jin, Nozawa, Shunsuke, Adachi, Shin-ichi, Yoon, Kihwan, Kim, Joonghan, Ihee, Hyotcherl
Formato: Artigo
Lenguaje:Inglês
Publicado: The Royal Society of Chemistry 2020
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC8179290/
https://ncbi.nlm.nih.gov/pubmed/34163975
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc05108j
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