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Femtosecond X-ray solution scattering reveals that bond formation mechanism of a gold trimer complex is independent of excitation wavelength
The [Au(CN)(2)(−)](3) trimer in water experiences a strong van der Waals interaction between the d(10) gold atoms due to large relativistic effect and can serve as an excellent model system to study the bond formation process in real time. The trimer in the ground state (S(0)) exists as a bent struc...
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| Publicado no: | Struct Dyn |
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| Main Authors: | , , , , , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
American Crystallographic Association
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4851617/ https://ncbi.nlm.nih.gov/pubmed/27191012 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1063/1.4948516 |
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