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Organophosphorus-catalyzed relay oxidation of H-Bpin: electrophilic C–H borylation of heteroarenes
A nontrigonal phosphorus triamide (1, P{N[o-NMe-C(6)H(4)](2)}) is shown to catalyze C–H borylation of electron-rich heteroarenes with pinacolborane (HBpin) in the presence of a mild chloroalkane reagent. C–H borylation proceeds for a range of electron-rich heterocycles including pyrroles, indoles, a...
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| Publié dans: | Chem Sci |
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| Auteurs principaux: | , , , |
| Format: | Artigo |
| Langue: | Inglês |
| Publié: |
The Royal Society of Chemistry
2020
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| Sujets: | |
| Accès en ligne: | https://ncbi.nlm.nih.gov/pmc/articles/PMC8179051/ https://ncbi.nlm.nih.gov/pubmed/34163869 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc05620k |
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