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Broadband fluorescence reveals mechanistic differences in excited-state proton transfer to protic and aprotic solvents

Excited-state proton transfer (ESPT) to solvent is often explained according to the two-step Eigen–Weller model including a contact ion pair (CIP*) as an intermediate, but general applicability of the model has not been thoroughly examined. Furthermore, examples of the spectral identification of CIP...

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Vydáno v:Chem Sci
Hlavní autoři: Verma, Pragya, Rosspeintner, Arnulf, Dereka, Bogdan, Vauthey, Eric, Kumpulainen, Tatu
Médium: Artigo
Jazyk:Inglês
Vydáno: The Royal Society of Chemistry 2020
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On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC8163259/
https://ncbi.nlm.nih.gov/pubmed/34094165
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/d0sc03316b
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